Study of microwave non-thermal effects on hydrogen bonding in water by Raman spectroscopy

Authors: Han G, Liu F, Zhang T, Xu W, Zhang Y, Wu N, Ouyang S

Year: 2022 Sep 22

Category: Spectroscopy

Journal: Spectrochim Acta A Mol Biomol Spectrosc

DOI: 10.1016/j.saa.2022.121877

URL: https://pubmed.ncbi.nlm.nih.gov/36174402/

Abstract

Overview

The research focuses on the role of microwave chemistry in organic synthesis, specifically investigating microwave non-thermal effects through Raman spectroscopy of water.

Findings

  • Analysis was done comparing oil bath and microwave heating effects on pure water's Raman spectra.
  • The study confirmed the presence of microwave non-thermal effects which transform stable hydrogen bonds into less stable chain-like structures more rapidly than traditional heating.
  • Temperature variations significantly influence the OH stretch in the Raman spectrum, indicating disruption in hydrogen bond networks at higher temperatures, particularly under microwave conditions.
  • Results highlight a more severe disruption of hydrogen bonds under microwave heating compared to conventional methods, leading to faster transitions from fully to partially bonded structures.

Conclusion

This research enhances our understanding of how microwaves affect molecular structures on a non-thermal level, offering insights into the prolonged effects (>1 hour) of such exposure on water's hydrogen bond integrity. The implications may extend to concerns about microwave exposure and its effects on molecular structures in other biological contexts.

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